[{TcI(NO)(LOMe)(PPh3)Cl}2Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with a “Kläui?type” Ligand
M. Roca Jungfer, M. J. Ernst, A. Hagenbach, U. Abram – 2022
The reaction of [Tc-I(NO)(L-OMe)(PPh3)Cl] ({L-OMe}(-) = eta(5)-cyclopentadienyltris(dimethyl phosphito-P)cobaltate(III)) with Ag(PF6) gives two unexpected products: the dimeric technetium(I) complex [{Tc(NO)(L-OMe)(PPh3)Cl}(2)Ag](PF6) with a central Ag+ ion and the cationic Tc(II) compound [Tc(NO)(L-OMe)(PPh3)Cl](PF6). The products have been studied spectroscopically and by X-ray diffraction.
Title
[{TcI(NO)(LOMe)(PPh3)Cl}2Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with a “Kläui?type” Ligand
Author
M. Roca Jungfer, M. J. Ernst, A. Hagenbach, U. Abram
Date
2022
Identifier
10.1002/zaac.202100316
Citation
Zeitschrift für anorganische und allgemeine Chemie 2022, 648 (4),
Type
Text
